Reaction Mechanisms in Organic Chemistry
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Author: Balci, Metin Publisher: VCH ISBN: 9783527349647 Cover: HARDCOVER Date: 2022年01月 DESCRIPTION An accessible and step-by-step exploration of organic reaction mechanisms In Reaction Mechanisms in Organic Chemistry, eminent researcher Dr. Metin Balci delivers an excellent textbook for understanding organic reaction mechanisms. The book offers a way for undergraduate and graduate students to understand???rather than memorize???the principles of reaction mechanisms. It includes the most important reaction types, including substitution, elimination, addition, pericyclic, and C-C coupling reactions. Each chapter contains problems and accompanying solutions that cover central concepts in organic chemistry. Students will learn to understand the foundational nature of ideas like Lewis acids and bases, electron density, the mesomeric effect, and the inductive effect via the use of detailed examples and an expansive discussion of the concept of hybridization. Along with sections covering aromaticity and the chemistry of intermediates, the book includes: * A thorough introduction to basic concepts in organic reactions, including covalent bonding, hybridization, electrophiles and nucleophiles, and inductive and mesomeric effects * Comprehensive explorations of nucleophilic substitution reactions, including optical activity and stereochemistry of SN2 reactions * Practical discussions of elimination reactions, including halogene elimination and Hofmann elimination * In-depth examinations of addition reactions, including the addition of water to alkenes and the epoxidation of alkenes Perfect for students of chemistry, biochemistry, and pharmacy, Reaction Mechanisms in Organic Chemistry will also earn a place in the libraries of researchers and lecturers in these fields seeking a one-stop resource on organic reaction mechanisms. TABLE OF CONTENTS 1 Basic Concepts 1 2 Nucleophilic Substitution Reaction 50 3 Elimination Reactions 87 4 Addition Reactions to Alkenes 133 5 Carbonyl Compounds 181 6 Aromaticity 281 7 Reactive Intermediates: Carbocations 381 8 Reactive Intermediates Carbanions, Carbenes, and Nitrenes 424 9 Reactive Intermediates: Radicals and Singlet Oxygen 468 10 Pericyclic Reactions 500 11 Carbon-Carbon Coupling Reactions 537 Index 605
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