Nickel Catalysis in Organic Synthesis
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有機合成におけるニッケル触媒:手法と反応 Methods and Reactions Publisher: VCH ISBN: 9783527344079 Cover: HARDCOVER Date: 2020年01月 こちらの商品は学校・法人様向け(機関契約)のオンラインブック版がございます。 オンラインブックの価格、納期につきましては弊社営業員または当ECサイトよりお問い合わせください。 DESCRIPTION A comprehensive reference to nickel chemistry for every scientist working with organometallic catalysts Written by one of the world?s leading reseachers in the field, Nickel Catalysis in Organic Synthesis presents a comprehensive review of the high potential of modern nickel catalysis and its application in synthesis. Structured in a clear and assessible manner, the book offers a collection of various reaction types, such as cross-coupling reactions, reactions for the activation of unreactive bonds, carbon dioxide fixation, and many more. Nickel has been recognized as one of the most interesting transition metals for homogeneous catalysis. This book offers an overview to the recently developed new ligands, new reaction conditions, and new apparatus to control the reactivity of nickel catalysts, allowing scientists to apply nickel catalysts to a variety of bond-forming reactions. A must-read for anyone working with organometallic compounds and their application in organic synthesis, this important guide: -Reviews the numerous applications of nickel catalysis in synthesis -Explores the use of nickel as a relatively cheap and earth-abundant metal -Examines the versatility of nickel catalysis in reactions like cross-coupling reactions and CH activations -Offers a resource for academics and industry professionals Written for catalytic chemists, organic chemists, inorganic chemists, structural chemists, and chemists in industry, Nickel Catalysis in Organic Synthesis provides a much-needed overview of the most recent developments in modern nickel catalysis and its application in synthesis. TABLE OF CONTENTS Part I Reactions via Nickelacycles 1 1 Formation of Nickelacycles and Reaction with Carbon Monoxide 3 2 Transformation of Aldehydes via Nickelacycles 13 3 Transformation of Imines via Nickelacycles 29 4 Asymmetric C-C Bond Formation Reactions via Nickelacycles 39 Part II Functionalization of Unreactive Bonds 69 5 Recent Advances in Ni-Catalyzed Chelation-Assisted Direct Functionalization of Inert C-H Bonds 71 6 C-C Bond Functionalization 103 7 C-O Bond Transformations 123 Part III Coupling Reactions via Ni(I) and/or Ni(III) 151 8 Photo-Assisted Nickel-Catalyzed Cross-Coupling Processes 153 9 Cross-Electrophile Coupling: Principles and New Reactions 183 10 Organometallic Chemistry of High-Valent Ni(III) and Ni(IV) Complexes 223 Part IV Carbon Dioxide Fixation 249 11 Carbon Dioxide Fixation via Nickelacycle 251 12 Relevance of Ni(I) in Catalytic Carboxylation Reactions 285 Index 331
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