Organosilicon Chemistry - Novel Approaches and Reactions
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有機ケイ素科学 − 新しいアプローチと反応 Author: Tamejiro Hiyama (Editor), Martin Oestreich (Editor) Publisher: VCH ISBN: 9783527344536 Cover: HARDCOVER Date: 2019年12月 こちらの商品は学校・法人様向け(機関契約)のオンラインブック版がございます。 オンラインブックの価格、納期につきましては弊社営業員または当ECサイトよりお問い合わせください。 DESCRIPTION Provides a unique summary of important catalytic reactions in the presence of silicon A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant metals. In addition to the topics covered above, Organosilicon Chemistry: Novel Approaches and Reactions features chapters that look at Lewis base activation of silicon Lewis acids, silylenes as ligands in catalysis, and chiral silicon molecules. -The first book about this topic in decades, covering a broad range of reactions -Covers new approaches and novel catalyst systems that have been developed in recent years -Written by well-known, international experts in the areas of organometallic silicon chemistry and organosilicon cross-coupling reactions Organosilicon Chemistry: Novel Approaches and Reactions is an indispensable source of information for synthetic chemists in academia and industry, working in the field of organic synthesis, catalysis, and main-group chemistry. TABLE OF CONTENTS 1 Catalytic Generation of Silicon Nucleophiles 1 2 Si-H Bond Activation by Main-Group Lewis Acids 33 3 Si-H Bond Activation by Transition-Metal Lewis Acids 87 4 Metal-Ligand Cooperative Si-H Bond Activation 115 5 Cationic Silicon-Based Lewis Acids in Catalysis 131 6 Transition-Metal-Catalyzed C-H Bond Silylation 171 7 Transition-Metal-Free Catalytic C-H Bond Silylation 213 8 Silyl-Heck, Silyl-Negishi, and Related Reactions 241 9 Transition-Metal-Catalyzed Cross-coupling of Organosilicon Compounds 271 10 Lewis Base Activation of Silicon Lewis Acids 333 11 Hydrosilylation Catalyzed by Base Metals 417 12 Silylenes as Ligands in Catalysis 439 13 Enantioselective Synthesis of Silyl Ethers Through Catalytic Si-O Bond Formation 459 14 Chiral Silicon Molecules 495 Index 533
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