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Vibrational Spectra of Organometallics
出版済み 3-5週間でお届けいたします。
有機金属化合物の振動スペクトル：理論と実験データ Theoretical and Experimental Data Author: Maslowsky, Edward Publisher: Wiley ISBN: 9781119404651 Cover: HARDCOVER Date: 2019年02月 こちらの商品は学校・法人様向け（機関契約）のオンラインブック版がございます。 オンラインブックの価格、納期につきましては弊社営業員または当ECサイトよりお問い合わせください。  DESCRIPTION A comprehensive compilation of the available experimental and theoretical vibrational data for organometallic compounds and its role in evaluating the structures, bonding, and properties of these key compounds This unique book offers a thorough review of the literature dealing with vibrational data obtained using various phases, including matrices, reported for organometallic compounds from infrared spectra, Raman spectra, and several other techniques. It is the only one that compiles the available experimental and theoretical vibrational data on these compounds, and which discusses the importance of this information and its role in evaluating structures, bonding, and other important properties. It also treats the use of DFT and other theoretical calculations to analyze the vibrational data and to predict properties associated with these compounds. The book also includes vibrational data for organic species that form on metal and other surfaces. Vibrational Spectra of Organometallics: Theoretical and Experimental Data offers complete coverage of: Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Derivatives; Noncyclic Carbon Clusters and Unsaturated Hydrocarbon Derivatives; and Cyclic, Unsaturated Organometallic Derivatives. By summarizing work that has already been done on organometallic compounds, it serves as an important reference for those studying their vibrational spectra and will, in the end, lead to a clearer understanding of other research that needs to be done in order to help researchers determine new research directions. * An important reference for those studying the vibrational spectra of organometallic compounds * Gathers the existing experimental and theoretical vibrational data and discusses its significance in assessing structures, bonding, and other principle properties * Includes DFT methods for the interpretation of spectra, which has been one of the major developments of the last two decades Vibrational Spectra of Organometallics: Theoretical and Experimental Data is an important reference for researchers and practitioners in the areas of inorganic, organometallic, organic, and surface chemistry who have an interest in using vibrational data to characterize the bonding, composition, reactions, and structures of organometallic compounds, and organic species that are formed on various surfaces. TABLE OF CONTENTS Preface xi Part I Carbide, Alkylidyne, Alkylidene, Alkyl, and Alkane Compounds 1 1 Monocarbide Complexes 3 2 Terminal and Bridging Methylidyne (CH) and Other Alkylidyne Complexes 9 3 Terminal and Bridging Methylidene (CH2) and Other Alkylidene Complexes 13 4 Methyl Complexes 21 5 Methane and Other Alkane Complexes 37 6 Terminal and Bridged Ethyl Complexes 43 7 Propyl, Butyl, and Pentyl Complexes 49 8 Cycloalkyl and Cycloalkane Complexes 53 9 Saturated Heterometallacycle Complexes 55 10 Benzyl Complexes 59 11 Mixed Alkyl and Alkyl-Aryl Complexes 61 12 Surface Bound Alkyl, Alkane, and Alkyl-Metal Complexes 63 13 Alkyl, Alkylidyne, and Alkylidene Complexes with Other Functional Groups 69 14 Complexes with Metal-Metal Bonds 215 15 Halogenated Alkyl Complexes 225 Part I References 241 Part II Noncyclic Carbon-Clusters and Unsaturated Hydrocarbon Compounds 299 16 Linear Carbon Cluster Complexes 301 17 Ethynyl, Ethyne, and Related Complexes 309 18 Vinyl and Vinylidene Complexes 343 19 Ethene and Related Monoalkene Complexes 355 20 Allyl and Related Complexes 371 21 Allene and Related Complexes 387 22 Conjugated and Nonconjugated Diolefin and Related Complexes 391 Part II References 403 Part III Cyclic, Unsaturated Organometallic Compounds 427 23 Metal Complexes of Fullerenes and Other Nonlinear Carbon Clusters 429 24 Three-carbon Rings 433 25 Four-carbon Rings 435 26 Five-carbon Rings 441 27 Six-carbon Rings 547 28 Seven-carbon Rings 613 29 Eight-carbon Rings 615 30 Nine-carbon Rings 629 31 Ten-carbon Rings 631 32 Coupled Organic Ring Complexes 633 33 Fused Organic Ring Complexes 635 Part III References 661 Index 709
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